For hydrogen atom, the energy of the revolving E, is the sum of its kinetic energy ( ½ mv2) and potential energy ( –e2/r).
E = ½ mv2 – e2/r ----------- (4)
From equation (1)
mv2 = e2/r
Substituting the value of mv2 in (3)
E = ½ e2/r – e2/r
Or,
E = –e2/2r -------------(5)
Substituting the value of ‘r’ from equation (3) in (5),
E = – e2/2 × 4π2me2/n2h2
E = – 2 π2me4/n2h2
By using proper integer for ‘n’ (quantum number), we can get the energy for each orbit.
thank you so much for this.....very helpful
ReplyDeleteMany many thanks. Can you pl give the derivation of schrodinger's equation and de Broglie's equation? It will be helpful for us.
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